Much of the understanding in soft material self-assembly has been from a thermodynamic perspective, although most self-assembly conditions are non-equilibrium. To understand how non-equilibrium conditions impact the resulting morphology, the self-assembly process of both a co-surfactant and a block copolymer system was investigated. In the case of the block copolymer, the self-assembly process resulted in materials that were organized at both the nano and the microscale, which led to interesting structured color properties.